Iupac nomenclature for organic compounds

IUPAC Rules for Nomenclature:

(i).Root words:

C1 -Meth, C2 -Eth, C3-Prop ,C4-Buta, C5- Penta, C6- Hexa, C7- Hepta,C8- Octa,C9-Nona,C10-Deca

(ii).Primary suffix:

                               Alkane   - C-C-       -ane
                               Alkene     -C=C-       -ene
                             alkyne       -C=_C-      -yne
1.Longest sum rule:
the longest continuous chain of carbon atoms is considered for naming the carbon compound, the prefix in the name of the compound depends on the number of carbons present in the compound.

2.Least Sum Rule:
In numbering the carbon atoms in the parent chain start at the end which  results in the use of lowest number for the substituent carbon atoms.

3.When identical substituent are present on the same carbon atom,the position of the substituent is repeated

4.if the carbon chain contain 2 or more than 2 identical substituent,then di- tri- tetra- words are used to indicate the number of substituents.

5.If the number of different groups are attached to the parent the chain ,then the naming is done in two ways:
(i). according to the IUPAC rules
(ii) the name is given to the compound following the increase in order of complexity of the group

6.when a carbon compound  has carbon chain having the same no.of carbon atoms,they having more number of branches is selected as the parent chain

7 If a carbon chain contains substituents which are at equal distance either from left are right side counting is done in such a way that the least number is given to substituens

8 When the main carbon chain in a carbon compound carries a branch which again contains a substituent,the position of the substituent in the branch is written in the brackets.

IUPAC Rules for naming Poly functional compounds:

A molecule can contain more than one functional group called as polyfunctional group,the functional group which specifies its class is called the principle functionl group the other functional groups are refered to as ' substituents'

Nomenclature Priority for determining the principle functional group.Highest priority at the top.
suffixes for functional groups:
Caboxylic acid     -COOH   (  -oic acid )
sulphonic acid    -SO3H  (sulphonic acid)
Ester                     - COOR ( -alkyl -  oate)
Acid halide           -COX  ( -oyl chloride)
amide                  -CO NH2 ( -amide)
nitrile                  -CN (-nitrile)
aldehyde         -CHO  (-al)
ketone             -CO-   (-one)
alcohol          -OH ( -ol)
amine             - NH2  (-amine)
ethers            -O-  (ether)
alkene          -C=C- (ene)
alkyne         -C=_C-   (-yne)


1.Identify principal functional group.this gives class name of  the structure.

2. Number the longest chain containing the principal functional group from the end closer to it.

3.Write the parent name corresponding to the no.of cabons in the longest chain.

4 Arrange the substituents names with position numbers in alphabetical order.

5.Prefix substituent name with the parent name.

6.The following functional groups are always named as substituents ,their names prefixed with the parent name.
ex:Cl - chloro; Br - bromo ;I -iodo ;F-flouro ;CN - cyano ; R - alkyl, OR - alkoxy ; NH2 -amine;NO2 -nitro  etc..

IUPAC Nomenclature rules with example:

7.Identify double/triple bonds. Number them with the number of the carbon atom at the head of the bond (i.e the carbon atom with the lesser number that it is attached to). For example a double bond between carbon atoms 3 and 4 is numbered as 3-ene. Multiple bonds of one type (double/triple) are named with a prefix (di-, tri-, etc.). If both types of bonds exist, then use "ene" before "yne" e.g. "6 13 diene 19 yne". If all bonds are single, use "ane" without any numbers or prefixes.

8. Arrange everything like in  this way: Group of side chains and secondary functional groups with numbers made in step 3 + prefix of parent hydrocarbon chain (eth, meth) + double/triple bonds with numbers (or "ane") + primary functional group suffix with numbers.
      Wherever it says "with numbers", it is understood that between the word and the numbers, you use the prefix(di-, tri-)

   9. Add punctuation:
         1. Put commas between numbers (2 5 5 becomes 2,5,5)
         2. Put a hyphen between a number and a letter (2 5 5 trimethylhexane becomes 2,5,5-trimethylhexane)
         3. Successive words are merged into one wordform (trimethyl hexane becomes trimethylhexane)
            NOTE: IUPAC uses one-word names throughout. This is why all parts are connected.

Ex:  CH3-CH(OH)-CH2-CH(CH3)-COOH

         5       4             3         2               1

From priority order -COOH  have higher rank ,therefore -COOH is the principal functional group.the structure is named as a carboxylic acid.
Longest chain : 5 carbons
so,parent name = pentanoic acid
Order of substituent 4-hydroxy -2-methyl
therefore,Name of the compound : 4-Hydroxy-2-methyl pentanoic acid.

Sound wave absorption

 Introduction :                                            
Sound waves travel in air as progressive longitudinal waves. Elasticity and inertia of the air  enable the sound wave to propagate with certain velocity. Sound cannot be transmitted through vacuum. It can travel through any solid, liquid and gas. All the frequencies of the vibrating bodies can not produce the sensation of hearing.

Sound  is a type of energy propagated in longitudinal waves. The source of sound could be any body which is vibrating. Some of the  examples are  a tuning fork which is excited, the wire of a stringed instrument being plucked , a bell which is struck with a hard thing,  etc.  When a sound wave is incident on any surface, a part of  the incident energy is always absorbed. Absorbption of  sound energy  vary  with different substances.

Thick screens or curtains, mats, carpets, wood, card boards are some of the examples of sound absorbers. Human bodies are very good absorbers of sound.  Best absorbers are those which absorb sound completely. Open windows and doors are therefore perfect absorbers. The characteristic absorption of a surface can be different at different frequencies.

Absorption coefficient of sound wave:

Absorption coefficient :  The absorption coefficient of a surface is defined as the ratio of the sound energy absorbed by the surface to the sound energy absorbed by an open window of equal area in the same time.

If Es  and Ew  are the amounts of sound energies absorbed by a given surface and an open window of the same area during same time, then

              The absorption coefficient        a     =    `(Es)/(Ew)`

Thus if  'a'  is the absorption coefficient of a surface and s is the surface area, the sound energy absorbed by it is given by  A  =  as.  Absorption coefficient 'a' has no unit but the SI unit of 'as' is metric sabin.

The absorption coefficients of certainsubstnces at a frequency of 512 Hz are given below.

S.No          Substance             Absorption Coefficient

1.               Marble                         0.01

2.               Glass                            0.028

3.               Carpet                          0.2

4.               Heavy Curtains             0.52

5.                Fibre glass                   0.69

6.              Open window                1.00

Doppler effect sound

Change in frequency of a wave for an observer which is moving with respect  to the source is called Doppler Effect. It was first proposed by Austrian physicist Christian Doppler in 1842. In day to day life we observe this phenomenon when a vehicle sounding a siren moves towards or away from an observer. The received frequency is higher (compared to the original emitted frequency) when source is coming nearer, it is identical at the instant of passing by, and it is lower when souce is moving away.

In mathematical form we write Doppler Effect as follows:
f= (V + Vr) / (V + Vs) * fo
Where:
V is the velocity of sound waves in the medium

Vr is the velocity of the receiver relative to the medium; taken positive if the receiver is moving towards the source.

Vs is the velocity of the emitting sound source relative to the medium; taken positive if the source is moving away from the receiver.

The frequency is decreased if either receiver or sound source moving away from the other.
Analysis

In Doppler Effect actually the frequency of the sounds that the source emits does not change. Let’s take a daily life example to understand what really happens. Suppose you throw one ball every second in your friend's direction. Assume that balls travel with constant velocity. If you are stationary, your friend will receive one ball every second. However, if you are moving towards your friend, he will receive balls more frequently because the balls will be less spaced out. The inverse is true if you are moving away from your friend. So it is actually the wavelength which is affected; as a consequence, the received frequency is also affected. It may also be said that the velocity of the wave remains constant whereas wavelength changes; hence frequency also changes.

Reflection of sound waves

A bell ringing rapidly, a drum moving up and down to the beat and a reverse rating harp string are all examples of objects that make sounds.
In this article let us learn about the reflection of sound waves.

Learning reflection of sound waves

Have you ever shouted into a well or inside an empty hall or in a cave? One can hear their own voice after a short time. Why is it happenning ? It happens because the sound of your voice is reflected from the walls.
We can also try this by shouting  into a well or by the side of a steep hill. This phenomenon of hearing your own sound again is called an echo. The rolling of thunder is largely due to successive reflections from clouds and land surfaces. For the reflection of sound waves, we need an extended surface, or obstacle of large size which need not necessarily smooth or polished.

Learning reflection of sound waves from one medium to other:

Generally, when sound waves in one medium strike a large object of another medium such as air, a wall, etc… , a part of the sound is reflected, and the remainder is sent into the new medium. The speed of the sound in the two mediums and the densities of the medium help to determine the amount of reflection. If the sound travels at about the same speed in both the materials and both have about the same density, little sound will be reflected, instead most of the sound will be transmitted into the new medium. If the speed differs greatly in the two and their densities are greatly different, most of the sound will be reflected.
When you shout at a brick wall most of the sound is reflected, because brick is denser than air.

I like to share this Sound Wave Energy with you all through my blog.

Check my best blog Sinusoidal wave equation.

Sinusoidal wave equation

We found that the disturbance (whether pulse or wave, transverse or longitudinal) depends on both position x and time t. If we call the displacement y, we can write y = f(x,t) or y(x,t) to represent this functional dependence on time and position. In the example of the transverse pulse traveling along a Slinky as pictured in Fig. 17-2,

y(x,t) represents the transverse (vertical) displacement of the Slinky rings from their equilibrium position at given position x and time t. (Alternatively, in the longitudinal wave on the Slinky shown in Fig. 17-1, y(x,t) could represent the number of Slinky coils per centimeter at a given x and t.)
We can completely describe any wave or pulse that does not change shape over time and travels at a constant velocity using the relation y = f(x,t), in which y is the displacement as a function/of the time t and the position x. In general, a wave can have any shape so long as it is not too sharp. The trick then is to find the correct expression for the function, f(x,t).

Fortunately, it turns out that any shape pulse or wave can be constructed by adding up different sinusoidal oscillations. This makes the description of sinusoidal waves especially useful. So, for the rest of this section we'll discuss the properties and descriptions of continuous waves produced by displacing a stretched string using a sinusoidal motion like that shown in Fig. 17-3b. We will start by using the equation we developed in Chapter 16 to describe for sinusoidal motion at the location of a single piece of string. As we did in looking through the slit in Fig. 17-5, we will only let time vary. Next we can consider how to describe a snapshot that records the displacement of many pieces of the string at a single time. Finally, we can combine our snapshot with the results of peeking through a slit to get a single equation that ought to describe the propagation of a single sinusoidal wave. Basically we are trying to describe the displacement y of every piece of the string from its equilibrium point at every time. We are looking for y(x,t).

Looking Through a Slit: Sinusoidal Wave Displacement at x = 0
If we choose a coordinate system so that x = 0 m at the left end of the string in Fig. 17-3b, then the motion at the left end of the string can be described using Eq. 16-5 with the string displacement from equilibrium represented by y(x,t) = y(0,r) rather than by simply y(t). To simplify our consideration we assume that the initial phase of the string oscillation at x = 0 m and t = 0 s is zero. This gives us

where the angular frequency can be related to the period of oscillation by to = 2irlT. Although we use the cosine function in Chapter 16 to describe simple harmonic motion, it is customary to use the sine function to describe wave motion. As we mentioned in Chapter 16, when a sine function is shifted to the left by v/2 it looks like a cosine function. So we can also describe the same string displacement as a function of time at x = 0 m as

Note that using the sine function requires a different, nonzero initial phase angle given by ir!2. If we locate our slit at another nonzero value of x as shown in Fig. 17-5, then the initial phase (at t = 0 s) will often turn out to be different from w/2. In fact this initial phase is a function of the location x of the piece of string we are considering.
A Snapshot: Sinusoidal Wave Displacement at t = 0

Imagine that the man has been moving the end of the string up and down as shown in Fig. 17-36 for a long time using a sinusoidal motion. Instead of looking through a slit as time varies, we take a snapshot of the string at a time t = Os similar to that shown in Fig. 17-36. Then we expect our snapshot to be described by the equation

where A: is a constant and the "initial" phase when x is zero must also be tt!2. Note that if the snapshot of the string were taken at another time, the initial phase would probably be different.

Combining Expressions for x and t
Equation 17-1 describes the displacement at all times for just the piece of string located at x = 0 m. Equation 17-2 describes the displacement of all the pieces of string at t = Os. We can make an intelligent guess that the equation describing y(x,t) is some combination of these two expressions given by
y(x,t) = Ysin[(foc ± cot) + tt/2)], (17-3)

where tt/2 represents the initial phase when x = 0 m and t - 0 s for the special case we considered. 

In general we can describe the motion of our sinusoidal wave with an arbitrary initial phase by modifying Eq. 17-3 to get
 y(x,t) = Ysin[(fct ± tot) + 4>q)] (sinusoidal wave motion, arbitrary initial phase), (17-4)
where <f>₀ is the initial phase (or phase constant) when both x = Om and t = Os. The ± sign refers to the direction of motion of the wave as we shall see in Section 17-5. In cases where the initial phase is not important, we can simplify Eq. 17-3 by choosing an initial time and origin of the x axis that lies along the line of motion of the wave so that <t>o = 0 rad.

Atomic number 28

Introduction :
d – block elements are also called transition elements. Transition metals are those elements which contain partially filled d- sub shells either in their atoms or in their common oxidation states. Nickel is a silvery white metal and takes a high polish. Nickel is hard malleable, ductile, ferromagnetic and fair conductor of heat and electricity. Atomic number 28 belongs to Iron – cobalt group. 'Ni' is commercially obtained from pentlandite and pyrrholite of the subdury region of Ontario.
Characteristics of Atomic number 28:

• The element in the periodic table which has atomic number 28 is Nickel. 
• 'Ni' has mass number 58.6934. 
• 'Ni' has oxidation state of 2 and 3. 
• Atomic number 28 has electronic configuration [Ar]4s²,3d⁸. 
• Nickel has chemical formula ‘Ni’.
• Atomic number 28 belong to Period 4 and Group 10.
• 'Ni' belongs to d - block elements. 

Properties of atomic number 28:

• Oxidation states of 'Ni': The elements exhibit variable oxidation states depending on the number of electrons participating in the bonding. Ni has oxidation states 2 and 3. 
• Colors of transition metal ions:  When the visible light of wavelength 400 to 700 nm is passed through a solution of a transition metal compound, it absorbs a particular frequency of radiation and transmits the remaining colors.
• Magnetic properties of 'Ni':  The paramagnetic behavior is highly pronounced in case of iron, cobalt and nickel. Hence they are called ferromagnetic substances.
• Formation of complexes by 'Ni': These metal ions have a great tendency to combine with a large number of molecules or ions called ligands and form complexes. The bond between a metal ion and a ligand is coordinate. Hence, complex compounds are also known as coordination compounds.
• Chemical reaction: Nickel carbonyl can be oxidized, Chlorine oxidizes nickel carbonyl into NiCl₂, releasing carbon monoxide gas.

               2Ni(CO)₄  +  2ClCH₂CH=CH₂    ====>  Ni₂(μ-Cl)₂ (η³-C₃H₅)₂  +  8CO

• Catalytic properties of transition metals: Many transition metals and their compounds are used as catalysts in several inorganic and organic chemical reactions. Nickel catalyst is used in the hydrogenation of oils.                                                                                       Oils +  H₂    →  Fats
• Isotopes of Nickel: ⁵⁸Ni, ⁶⁰Ni, ⁶¹Ni, ⁶²Ni and ⁶⁴Ni are five stable isotopes of Nickel. ⁵⁸Ni being the most abundant.  ⁶²Ni is one of the most stable nuclides.
• Reaction of 'Ni' with halogens:

             Ni_(s)    +    cl_2(g)   ====>    NiCl_2(s)     (Yellow)
             Ni_(s)    +    Br_(g)    ====>    NiBr_2(s)     (Yellow)
             Ni_(s)    +    I_2(g)     ====>    NiI_2(s)       (black)

• Reaction of Nickel with acids:

             Ni_(s)     +   H₂SO_4(aq)  ====>  Ni²⁺_(aq)  +  SO^2-_(aq)  +  H_2(g)  

• Reaction of Nickel with air:

    Nickel metal does not react with air under normal condition. Finely divided Nickel metal readily reacts with air. At higher temperatures, the reaction appears not to proceed to completion but give some nickel(ll) oxide.
            2Ni_{(s)    +}    O_2(g)    ====>  2NiO_(s)                                                                                        

Uses of Atomic number 28:

• It is used in many industrial and consumer products, including stainless steel, magnets, coins, rechargeable batteries, electric guitar strings and special alloys. 
• 'Ni' is used in plating and as a green tint in glass. 
• Atomic number 28 is a metal alloy and its chief use in the nickel steels and nickel cast iron. 
• 'Ni' is widely used in many alloys, such as nickel brasses and nickel bronze. etc.
• Raney Nickel, a finely divided form of metal is alloyed with aluminum which absorbs hydrogen gas. 

Isotopes of carbon

Introduction to Carbon:
The element with atomic number 6 in the periodic table refers to Carbon which belongs to group 14.  This element is widely distributed in most of the planets.  Carbon is a nonmetallic and tetravalent element and it forms covalent bonds.  The common oxidation states of carbon are +4 in organic compounds and +2 in carbon monoxide and transition metal complexes.  Diamond is the hardest material of carbon where as ceraphite is the softest material.   Mainly there are three allotropes of carbon fullerenes, diamond and graphite and some other forms are ionsdaleite, buckminsterfullerene and also carbon nanotube.
Allotropic forms of element with atomic number 6:
Fullerene                                 
     

Isotopes of carbon:

Among seven isotopes carbon has two stable isotopes. Those two isotopes of carbon are carbon-14 which is a naturally occurring radioisotope, it is used in carbon dating. Carbon- 13 which forms only 1.07%. Carbon-8 is the shortest lived isotope. Carbon-19 is the isotope which exhibits nuclear halo.
Compounds of carbon:
In atmosphere, carbon is found in combination with other elements like oxygen, hydrogen etc.  For ex: carbon dioxide, carbon monoxide, carbon disulfide, carbon tetra fluoride, chloroform, carbon tetrachloride, methane, ethylene, acetylene , benzene , acetic acid its derivatives.
Organic compound containing carbon (carbon tetra fluoride):

Properties of carbon:

• Atomic mass: 12
• Appearance: solid
• Electronic configuration: 1s² 2s² 2p² or [He] 2s² 2p²
• Density: 1.8-3.5g/cm³
• Melting point: 3915K
• Oxidation states: +4, +2
• Vander walls radius: 170pm

Applications of carbon:
1. Without carbon life could not exist because it plays an important role.
2. Carbon-14 which is naturally occurring isotope is used in carbon dating.
3. Allotrope of carbon (graphite) is used in pencil leads.
4. Hydrocarbons in combination with carbon are used in the production of gasoline and kerosene.
5. In nuclear reactors, it is used as neutron moderator.
6. It is (charcoal) used in artwork as a drawing material.
7. Cellulose is a natural carbon containing polymer used in maintaining the structure of plants.
8. Synthetic carbon is used in the production of plastics
9. It is used in diamond industries.

10. Now a day’s used in the production of carbon nanotube.