Wednesday, November 21, 2012

Definition of some Important Terms Pertaining to Coordination Compounds


Introduction:
Complex ion, exciting molecular collective consisting of a metallic atom or ion to which is emotionally involved single or additional electron-donating molecules. In a number of complex ions, such as sulfate, the atoms are so tightly bound collectively that they do something as an only unit. A lot of complex ions however are simply loosely aggregated and lean to distance in a water solution until equilibrium is recognized connecting the complex ion and its important components.

Some Important Terms Pertaining to Coordination Compounds:

Definition of Central atom/ion compounds:
In terms pertaining of coordination entity is definition; the atom/ion to which a fixed number of ions/group is bound in a definite geometrical arrangement around is called the central atoms or ions.
Ligands compounds:
The terms pertaining ions or molecules bound to the central atoms ion in the coordination entity are called ligands. These may be simple ions such as Cl-, Small molecules such as H2o or NH3, larger molecules such as H2NCH2CH2NH2 or N (CH2CH2NH3) or even macromolecules such as proteins.
Definition of coordination number:
Some terms pertaining of synchronization numeral of a metal ion in a complex can be distinct as the number of ligands donor atoms to which the metal is straight bonded.
Definition of coordination sphere:
The central atom/ions and ligands attached to it are enclosed in square, bracket and are collectively terms pertaining as the coordination sphere. Some ionization groups are written outside the bracket and are called counter ions.
Definition of coordination polyhedron:
The spatial arrangements of the important ligand atoms which are directly attached to the central atoms/ion definition terms a coordination polyhedron about the central atoms.
Definition of oxidation number of central atoms compounds:
The oxidation number of the central atom in a some complex is definition as the charge it would carry if all the ligands are removed along with the electron pair that are shared with the central atoms.

Homoleptic and Heteroleptic Complexes Compounds:

         Important complex in which a metal is bound to only one kind of donor group [CO (NH3)6)3+ are known as homoleptic. Important Complex in which a metal is bound to more than one kind of donor group are known as hetroleptic.

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